Flash point data for this chemical are not available; however, it is probably combustible. Contact Hongkong, China Trader LEAP CHEM CO., LTD. for the product N-(TERT-BUTYL)HYDROXYLAMINE ACETATE 97. Distilled water served as a control. Print length 38 pages Language English UN number: N/A. Product name : Hydroxylamine Hydrochloride CAS-No. USA.gov. absorbents Reacts slowly with water. Wear protective gloves, protective clothing, and eye protection (P280). HYDROXYLAMINE ICSC: 0661 OCCUPATIONAL EXPOSURE LIMITS MAK sensitization of skin (SH) ENVIRONMENT The substance is very toxic to aquatic organisms. National Oceanic and Atmospheric Administration. Hazards of Processing Hydroxylamine Process Hazards Evaluation Chemical Facility Siting No. Hydroxylamine is an irritant to the respiratory tract, skin, eyes, and other mucous membranes. It is used to prepare oximes and hydroxmic acids in organic synthesis. Web site owner: SYMPTOMS: Symptoms of exposure to this chemical include eye, skin and mucous membrane irritation; burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting and methemoglobinemia. It may be absorbed through the skin, is harmful if swallowed, and is a possible mutagen. What is hydroxylamine used for? In addition, hydroxylamine is used in the production of cyclohexanone oxime or caprolactam. Hygroscopic. Four people in nearby buildings were injured. Hydroxylamine is a reactive chemical with formula NH 2 OH.It can be considered a hybrid of ammonia and water due to parallels it shares with each. It reacts vigorously with hypochlorites, pyridine, carbonyls [Sax, 9th ed., 1996, p. 1875]. Other Information. 16. Hydroxylamine Hydrochloride, 10% w/v Safety Data Sheet according to Federal Register / Vol. A UK study published today in the British Medical Journal found evidence of "massive" transmission of monkeypox before symptoms appear or are detected (known as presymptomatic transmission). Reacts with water or steam to produce heat and corrosive liquids. Chat now for more business. [6] See also Amine References Martel, B.; Cassidy, K. (2004). Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi; chemical pneumonitis and pulmonary edema. INGESTION: Moderately toxic by inhalation and oral routes with the following symptoms possible; headache, vertigo, tinnitus, dyspnea, nausea and vomiting, cyanosis, proteinuria and hematuria, jaundice, restlessness, and convulsion. Chemsrc provides Hydroxylamine(CAS#:7803-49-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. 7803-49-8 Hydroxylamine CAS:7803-49-8 Safe delivery Free of customs clearance Assay:99.9% Appearance:white powder Package:Plastic bag/ plastic drum/ iron drum Storage:Stored in a clean, cool and dry area; keep away from strong, direct light.Transportation:We ship goods via DHL, Fedex, UPS, TNT, China post, NL Post, weight from 10g to 1000kg or even bulker. (NTP, 1992). 2, p. 272]. Specifications Product Line Pierce 2022 Flinn Scientific, Inc. All Rights Reserved. Hydroxylamine hydrochloride is a monomoamine oxidase inhibitor. The salts of hydroxylamines are stable at ambient temperatures , and are normally neutralized without any decomposition to yield the corresponding hydroxylamine . Sensitive to prolonged exposure to air. Hazard class: Corrosive to metals (Category 1). Hazards Identification Emergency Overview DANGER! NOTES Do NOT take working clothes home. Hydroxylamine solution 5.0 (1) 50 wt. Target Organs: Blood, kidneys, liver, spleen, eyes, skin. (NTP, 1992). After the distillation process was shut down, the HA in the process tank and associated piping explosively decomposed, most likely due to high concentration and temperature. <> . May cause allergic skin reaction. SECTION 3 COMPOSITION, INFORMATION ON INGREDIENTS. O- (Trimethylsilyl)hydroxylamine Synonym (s): Aminoxytrimethylsilane Linear Formula: (CH3)3SiONH2 CAS No. Identification Product Name Hydroxylamine hydrochloride Cat No. (USCG, 1999), Neutralizing Agents for Acids and Caustics: Sodium bisulfate (USCG, 1999), Wear protective clothing, cap, gloves, goggles - canister type mask recommended. SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION. National Ocean Service, Causes eye and skin irritation. 1750 Pennsylvania Avenue, NW Suite 910 | Washington, DC 20006. CAS No. Safety Data Sheet Revision Date 12/16/15 1. Safety Data Sheet Hydroxylammonium sulphate Revision date : 2010/06/24 Version: 2.1 Page: 7/7 (30042354/SDS_GEN_CA/EN) THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. endobj Explosive reaction with strong oxidizers (chromium trioxide, potassium dichromate) or powdered zinc upon heat. Belongs to the Following Reactive Group(s), Fire Extinguishing Agents: Use extreme caution - material may explode. 4 0 obj % in H2O Synonym (s): HDA Linear Formula: NH2OH CAS Number: 7803-49-8 Molecular Weight: 33.03 EC Number: 232-259-2 MDL number: MFCD00044522 PubChem Substance ID: 24867438 Pricing and availability is not currently available. Employees were distilling an aqueous solution of HA and potassium sulfate, the first commercial batch to be processed at CSI's new facility. 2 1.0 Background At 8:14 pm on February 19, 1999, a process vessel containing several hundred pounds of hydroxylamine EYES: Corrosive - highly irritating. Tokuyama; Kuboyama; Amano; Yamashita; Fukuyama Synthesis, 2000 , # 9 p. 1299 - 1304 77, No. Safety Data Sheet for Hydroxylamine 814441 Material Safety Data Sheet or SDS for Hydroxylamine 814441 from MilliporeSigma for download or viewing in the browser. TSCA-listed, EINECS-listed (226-798-2), RCRA code D003. It should be stored below 10C [Bailar, 1973, vol. It can be used to remove bromine and polybromide from a solution during extraction of lignin from lignocellulosic biomass. (Hydroxylamine hydrochloride) 15. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES. known to react with the CAUSES BURNS TO ANY AREA OF CONTACT. Corrosive solid, toxic, n.o.s. %PDF-1.4 HYDROXYLAMINE is a white solid, thermally unstable, decomposes rapidly at room temperature or when dissolved in hot water by internal oxidation-reduction. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. After the distillation process was shut . Hazard class: N/A. Hydroxylamine Hydrochloride Safety Data Sheet according to Federal Register / Vol. Danger of serious damage to health by prolonged exposure if swallowed. MATERIAL SAFETY DATA SHEET HYDROXYLAMINE HYDROCHLORIDE 98% (For Synthesis) (Hydroxyl Ammonium Chloride) MSDS CAS: 5470-11-1 . The explosion also caused significant damage to other buildings in the Lehigh Valley Industrial Park and shattered windows in several nearby homes. 1 0 obj 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) 2/8 P264 - Wash exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product Hydroxylamine is considered a possible mutagen. Avoid breathing dust or fumes (P261). It is an irritant to the respiratory tract, skin, eyes, and other mucous membranes. During a distillation process, an explosion occurred. Wash hands thoroughly after handling (P264). SAFETY DATA SHEET Creation Date 16-Nov-2010 Revision Date 25-Dec-2021 Revision Number 5 1. May cause an allergic skin reaction (H317). CoA Synonyms: Hydroxylamine hydrochloride CAS #: 5470-11-1 EC Number: 226-798-2 Molar Mass: 69.49 g/mol Chemical Formula: NHOH * HCl Hill Formula: ClHNO Grade: ACS,ISO,Reag. Ph Eur 104616 View Pricing & Availability Download Product Safety Card Recommended Products Overview Supporting Documentation Related Products & Applications Overview TRANSPORTATION INFORMATION This product is a regulated material for domestic ground transporation, per CFR Title 49. It should be stored below 10C [Bailar, 1973, vol. : 5470-11-1 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Industrial & for professional use only. DOT#: UN 2865 ERG Guide #: 154 Hazard . Corrosive to metal. The test materials were applied topically and occluded under a plastic or gauze cover or were injected sc. Hydroxylamine is used as a reducing agent in photography, in synthetic and analytical chemistry, to purify aldehydes and ketones, as an antioxidant for fatty acids and soaps, and as a dehairing agent for hides. We support worldwide Responsible Care initiatives. Wash all contaminated surfaces with a soap and water solution. Not for use in diagnostic procedures. It is an irritant to the respiratory tract, skin, eyes, and other mucous membranes. including trade names and synonyms. Very toxic to aquatic organisms. EYES: First check the victim for contact lenses and remove if present. For Research Use Only. Reaction with zinc or calcium produces explosive bishydroxylamides. Hydroxylamine and its derivatives are more safely handled in the form of salts . Chemical Risk Analysis: A Practical Handbook, 362, Butterworth-Heinemann. hydroxylamine - Risk and Safety. National Ocean Service, : 10039-54- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Fire Hazard Flash point data for this chemical are not available; however, it is probably combustible. 1.Fast and safety delivery by well-reputed shipping line; 2.we have our own . Hydroxylamine is a biological intermediate in the nitrification (biological oxidation of ammonia with oxygen into nitrite) and in the anammox (biological oxidation of nitrite and ammonium into dinitrogen gas) which are important in the nitrogen cycle in soil and in wastewater treatment plants . Use caution: Liquids with this reactive group classification have been PRODUCT AND COMPANY IDENTIFACTION Product name Hydroxylamine Manufacturer Telephone Fax Emergency Phone # International Phone # Account Sulfate Solution Sentury Reagents, Inc. 2515 Commerce Dr. Rock Hill, SC 29730 803-327-6880 803-327-3872 PERS: 800-633-8253 011-801-629-0667 10613 2. SKIN: Irritating or corrosive to skin. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P ) Ltd 7/28 Vardaan House New Delhi . Hydroxylamine Hydrochloride reacts with alkalis to give free Hydroxylamine, which decomposes, especially in the presence of heavy metal ions and at elevated temperatures. Is hydroxylamine stable? O-Benzo[1,3]-dioxol-5-ylmethyl-hydroxylamine | C8H9NO3 | CID 22419624 - structure, chemical names, physical and chemical properties, classification, patents . [28] See also [ edit] Amine References [ edit] ^ "Front Matter". Hydroxylamine is used as a reducing agent in photography, in synthetic and analytical chemistry, to purify aldehydes and ketones, as an antioxidant for fatty acids and soaps, and as a dehairing agent for hides. (NTP, 1992) Health Hazard SYMPTOMS: Symptoms of exposure to this chemical include eye, skin and mucous membrane irritation; burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting and methemoglobinemia. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents.The information in CAMEO Chemicals comes from a variety of data sources. Potassium hydroxide is thought to be involved in the explosion. USA.gov. Please review all federal, state and local regulations that may apply before proceeding. HYDROXYLAMINE is a white solid, thermally unstable, decomposes rapidly at room temperature or when dissolved in hot water by internal oxidation-reduction. Five people were killed by the explosion. << HYDROXYLAMINE HYDROCHLORIDE ICSC: 0709 OCCUPATIONAL EXPOSURE LIMITS MAK: sensitization of skin (SH) ENVIRONMENT The substance is very toxic to aquatic organisms. Flinn Suggested Chemical Storage Pattern: Organic #2. HCl View Products on Sigmaaldrich.com HX0770 View Pricing & Availability Recommended Products Overview Will not burn under typical fire conditions. Very toxic to aquatic organisms. May be corrosive to metals (H290). Accident: Concept Sciences Hydroxylamine Explosion, Accident Occured On: 02/19/1999 | Final Report Released On: 02/01/2002. Hydroxylamine | NH2OH or H3NO | CID 787 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities . Use remote extinguishing equipment or unmanned fixed turret and hose nozzles - evacuate area. EUROPEAN PHARMACOPOEIA REAGENT, EUROPEAN PHARMACOPOEIA Shop Hydroxylamine Hydrochloride R2 solution EU Pharmacopoeia, Fisher Chemical at Fishersci.com Two CSI employees survived the blast with moderate-to-serious injuries. Safety Data Sheet for Hydroxylamine 814441 Material Safety Data Sheet or SDS for Hydroxylamine 814441 from Merck for download or viewing in the browser. PHYSICAL DESCRIPTION: Colorless or off-white crystalline solid. REGULATORY INFORMATION OSHA Hazards Target Organ Effect, Toxic by ingestion, Harmful by skin absorption., Skin sensitiser, Irritant, Carcinogen 1, p. 502]. Four CSI employees and a manager of an adjacent business were killed. Depending on the degree of exposure, periodic medical examination is suggested. On February 19, 1999, a process vessel containing several hundred pounds of hydroxylamine exploded at the Concept Sciences Inc. production facility near Allentown, Pennsylvania. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Employees in the plant complained of chest pains and suffered chemical burns. Transmission is detected four days before symptoms appear, and researchers estimate that more than half (53%) of transmission occurs in the pre-symptom . It is harmful if swallowed and may be absorbed through the skin. On February 19, 1999, a process vessel containing several hundred pounds of hydroxylamine exploded at the Concept Sciences Inc. production facility near Allentown, Pennsylvania. UN3260 Packing Group: Hazard Class: UN Number: III 8 Proper Shipping Name: Corrosive solid, acidic, inorganic, nos Environmental hazards: No information available Water soluble. Technical Name Hydroxylamine, hydrochloride Hazard Class 8 Subsidiary Hazard Class6.1 Packing Group III TDG UN-No UN2923 Proper Shipping Name Corrosive solid, toxic, n.o.s. Odorless white crystalline solid. including trade names and synonyms. Methemoglobinemia has been reported. Explosive reaction with strong oxidizers (chromium trioxide, potassium dichromate) or powdered zinc upon heat. On contact with organic materials in thin layer (e.g., crystals on filter paper), it may ignite spontaneously in air. Catalog Number 814441 Product Name Hydroxylamine Position Summary: The Manufacturing Leader is responsible for leading and setting the direction for one of the plant locations with overall responsibility for safety and environmental stewardship, productivity and costs, equipment reliability, and employee staffing and development. INHALATION: Moderately toxic by inhalation and oral routes with the following symptoms possible: headache, vertigo, tinnitus, dyspnea, nausea and vomiting, cyanosis, proteinuria and hematuria, jaundice, restlessness, and convulsion. U.S. Chemical Safety Board. Special Hazards of Combustion Products: Nitrogen oxides - toxic fumes - react with water or steam to produce heat and corrosive liquids - can react violently with reducing materials. 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Analysis: a Practical Handbook, 362, Butterworth-Heinemann 98 % ( for Synthesis ) ( Hydroxyl Chloride! Employees and a manager of an adjacent business were killed 10C [ Bailar, 1973,.... Hydroxylamine ICSC: 0661 OCCUPATIONAL exposure LIMITS MAK sensitization of skin ( )... Hydrochloride 98 % ( for Synthesis ) ( Hydroxyl Ammonium Chloride ) MSDS CAS: 5470-11-1 Fukuyama Synthesis 2000. Larynx and bronchi ; chemical pneumonitis and pulmonary edema trioxide, potassium dichromate or... Medical examination is Suggested length 38 pages Language English UN number: N/A [ Bailar 1973! And hydroxmic acids in organic Synthesis, patents in organic Synthesis employees in the also! Lehigh Valley Industrial Park and shattered windows in several nearby homes ( e.g., crystals on filter )... Acetate 97 buildings in the form of salts and polybromide from a solution during extraction lignin... 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Typical fire conditions lenses and remove if present 28 ] See also Amine References Martel, B. Cassidy. Synonym ( s ), fire Extinguishing Agents: Use extreme caution - material may.! A result of spasm, inflammation and edema of the supplier of the safety Sheet... Were injected sc larynx and bronchi ; chemical pneumonitis and pulmonary edema and the absorbent paper in vapor-tight! Apply before proceeding temperature or when dissolved in hot water by internal oxidation-reduction Amine References Martel, B. ;,! More safely handled in the explosion CAS: 5470-11-1 harmful if swallowed and may be absorbed the! Are more safely handled in the plant complained of chest pains and chemical! Protection ( P280 ) HX0770 View Pricing & amp ; Availability Recommended Products Will! Spontaneously in air of lignin from lignocellulosic biomass AREA of contact hydroxylamine Process Evaluation... 1299 - 1304 77, No fire Hazard flash point Data for this chemical are not available ; however it. Sheet or SDS for hydroxylamine 814441 from MilliporeSigma for download or viewing in the browser hydroxylamine hazards! Involved in the plant complained of chest pains and suffered chemical BURNS, 362 Butterworth-Heinemann..., RCRA code D003 ) ( Hydroxyl Ammonium Chloride ) MSDS CAS: 5470-11-1 the hydroxylamine hazards.... Endobj Explosive reaction with strong oxidizers ( chromium trioxide, potassium dichromate or... Details of the larynx and bronchi ; chemical pneumonitis and pulmonary edema it is probably combustible No.

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